CobaltMaghrebV1, Main, Exploration, bibRecord, 000244

Bis(4-aminopyridinium) hexaaquanickel(II) bis(sulfate)

Identifieur interne : 000244 ( Main/Exploration ); précédent : 000243; suivant : 000245

Bis(4-aminopyridinium) hexaaquanickel(II) bis(sulfate)

Auteurs : Thameur Sahbani [Tunisie] ; Wajda Smirani Sta [Tunisie] ; Mohamed Rzaigui [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.

RBID : PMC:3914041

Abstract

In the title compound, (C₅H₇N₂)₂[Ni(H₂O)₆](SO₄)₂, the Ni^II cation is located on an inversion centre and is coordinated by six aqua ligands in a slightly distorted octahedral coordination environment. The [Ni(H₂O)₆]²⁺ ions are connected through an extensive network of O—H⋯O hydrogen bonds to sulfate anions, leading to the formation of layers parallel to (001). The 4-aminopyridinium cations are located between these layers and are connected to the anionic framework by N—H⋯O hydrogen bonds. Weak π–π interactions between the pyridine rings, with a centroid–centroid distance of 3.754 (9) Å, provide additional stability to the crystal packing.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914041

DOI: 10.1107/S1600536813032558
PubMed: 24526957
PubMed Central: 3914041

Affiliations:

Tunisie

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Bis(4-aminopyridinium) hexaaquanickel(II) bis(sulfate)</title>
<author><name sortKey="Sahbani, Thameur" sort="Sahbani, Thameur" uniqKey="Sahbani T" first="Thameur" last="Sahbani">Thameur Sahbani</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Smirani Sta, Wajda" sort="Smirani Sta, Wajda" uniqKey="Smirani Sta W" first="Wajda" last="Smirani Sta">Wajda Smirani Sta</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Rzaigui, Mohamed" sort="Rzaigui, Mohamed" uniqKey="Rzaigui M" first="Mohamed" last="Rzaigui">Mohamed Rzaigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PMC</idno>
<idno type="pmid">24526957</idno>
<idno type="pmc">3914041</idno>
<idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914041</idno>
<idno type="RBID">PMC:3914041</idno>
<idno type="doi">10.1107/S1600536813032558</idno>
<date when="2013">2013</date>
<idno type="wicri:Area/Pmc/Corpus">000376</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000376</idno>
<idno type="wicri:Area/Pmc/Curation">000375</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000375</idno>
<idno type="wicri:Area/Pmc/Checkpoint">000210</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">000210</idno>
<idno type="wicri:Area/Ncbi/Merge">000298</idno>
<idno type="wicri:Area/Ncbi/Curation">000298</idno>
<idno type="wicri:Area/Ncbi/Checkpoint">000298</idno>
<idno type="wicri:Area/Main/Merge">000245</idno>
<idno type="wicri:Area/Main/Curation">000244</idno>
<idno type="wicri:Area/Main/Exploration">000244</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Bis(4-aminopyridinium) hexaaquanickel(II) bis(sulfate)</title>
<author><name sortKey="Sahbani, Thameur" sort="Sahbani, Thameur" uniqKey="Sahbani T" first="Thameur" last="Sahbani">Thameur Sahbani</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Smirani Sta, Wajda" sort="Smirani Sta, Wajda" uniqKey="Smirani Sta W" first="Wajda" last="Smirani Sta">Wajda Smirani Sta</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Rzaigui, Mohamed" sort="Rzaigui, Mohamed" uniqKey="Rzaigui M" first="Mohamed" last="Rzaigui">Mohamed Rzaigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2013">2013</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en"><p>In the title compound, (C<sub>5</sub>
H<sub>7</sub>
N<sub>2</sub>
)<sub>2</sub>
[Ni(H<sub>2</sub>
O)<sub>6</sub>
](SO<sub>4</sub>
)<sub>2</sub>
, the Ni<sup>II</sup>
 cation is located on an inversion centre and is coordinated by six aqua ligands in a slightly distorted octahedral coordination environment. The [Ni(H<sub>2</sub>
O)<sub>6</sub>
]<sup>2+</sup>
 ions are connected through an extensive network of O—H⋯O hydrogen bonds to sulfate anions, leading to the formation of layers parallel to (001). The 4-aminopyridinium cations are located between these layers and are connected to the anionic framework by N—H⋯O hydrogen bonds. Weak π–π interactions between the pyridine rings, with a centroid–centroid distance of 3.754 (9) Å, provide additional stability to the crystal packing.</p>
</div>
</front>
<back><div1 type="bibliography"><listBibl><biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
</listBibl>
</div1>
</back>
</TEI>
<affiliations><list><country><li>Tunisie</li>
</country>
</list>
<tree><country name="Tunisie"><noRegion><name sortKey="Sahbani, Thameur" sort="Sahbani, Thameur" uniqKey="Sahbani T" first="Thameur" last="Sahbani">Thameur Sahbani</name>
</noRegion>
<name sortKey="Rzaigui, Mohamed" sort="Rzaigui, Mohamed" uniqKey="Rzaigui M" first="Mohamed" last="Rzaigui">Mohamed Rzaigui</name>
<name sortKey="Smirani Sta, Wajda" sort="Smirani Sta, Wajda" uniqKey="Smirani Sta W" first="Wajda" last="Smirani Sta">Wajda Smirani Sta</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000244 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000244 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    CobaltMaghrebV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     PMC:3914041
   |texte=   Bis(4-aminopyridinium) hexaaquanickel(II) bis(sulfate)
}}

Pour générer des pages wiki

HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i   -Sk "pubmed:24526957" \
       | HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd   \
       | NlmPubMed2Wicri -a CobaltMaghrebV1

This area was generated with Dilib version V0.6.32.
Data generation: Tue Nov 14 12:56:51 2017. Site generation: Mon Feb 12 07:59:49 2024

Serveur d'exploration sur le cobalt au Maghreb

Bis(4-aminopyridinium) hexaaquanickel(II) bis(sulfate)

Bis(4-aminopyridinium) hexaaquanickel(II) bis(sulfate)

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

	Serveur d'exploration sur le cobalt au Maghreb
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le cobalt au Maghreb

Bis(4-amino­pyridinium) hexa­aqua­nickel(II) bis­(sulfate)

Bis(4-amino­pyridinium) hexa­aqua­nickel(II) bis­(sulfate)

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

Bis(4-aminopyridinium) hexaaquanickel(II) bis(sulfate)

Bis(4-aminopyridinium) hexaaquanickel(II) bis(sulfate)